You don't know my name's Bond, James Bond

Alicia Keys is singing the new Bond theme with Jack White, apparently:

"Hello? Can I speak to -- to James? Oh hey, how you doin? Uh, I feel kinda silly doin' this, But um, this is the waitress from the casino on 39th and Lennox You know, the one with the braids? Yeah, well I see you on Wednesdays all the time You come in every Wednesday on your lunch break, I think And you always order the special, with the martini And my manager be tripping and stuff Talking bout we gotta stir 'em But I always shake yours Cause I think you're kinda sweet. Anyway you always got on some fly tuxedo 'n your cufflinks are shining all bright So, whatchu do? Oh, you're a spy? Yeah, that's interesting"

If that doesn't make any sense, try skipping to 3'40" in this.